Golf ball

ABSTRACT

A two-piece golf ball having a reaction injection molded polyurethane cover is disclosed herein. The golf ball has a core with a diameter preferably ranging from 1.610 inches to 1.670 inches, and a cover having a thickness preferably ranging from 0.015 inch to 0.045 inch. The cover also preferably has a plurality of deep apertures extending through the cover.

CROSS REFERENCES TO RELATED APPLICATIONS

The Present Application is a continuation application of U.S. patentapplication Ser. No. 11/164,448, filed Nov. 22, 2005, which is acontinuation-in-part application of U.S. patent application Ser. No.11/152,446, filed Jun. 13, 2005, which is a continuation application ofU.S. patent application Ser. No. 09/877,600, filed Jun. 8, 2001, nowU.S. Pat. No. 6,905,424, which is a continuation application of U.S.patent application Ser. No. 09/411,690, filed Oct. 1, 1999, now U.S.Pat. No. 6,290,614, which is a continuation-in-part application of U.S.patent application Ser. No. 09/040,798, filed Mar. 18, 1998, now U.S.Pat. No. 6,855,073. The present application is also acontinuation-in-part application of U.S. patent application Ser. No.10/305,531, filed on Nov. 27, 2002, which claims priority to U.S.Provisional Patent Application No. 60/337,123, filed Dec. 4, 2001; U.S.Provisional Patent Application No. 60/356,400, filed Feb. 11, 2002; andU.S. Provisional Patent Application No. 60/422,247, filed Oct. 30, 2002.

STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

Not Applicable

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a golf ball. More specifically, thepresent invention relates to a two-piece golf ball with an oversizedcore and a reaction injection molded polyurethane cover.

2. Description of the Related Art

Conventionally golf balls are made by molding a cover around a core. Thecore may be wound or solid. The cover is typically injection molded,compression molded, or cast over the core. Injection molding typicallyrequires a mold having at least one pair of mold cavities, e.g., a firstmold cavity and a second mold cavity, which mate to form a sphericalrecess. In addition, a mold may include more than one mold cavity pair.

In one exemplary injection molding process each mold cavity may alsoinclude retractable positioning pins to hold the core in the sphericalcenter of the mold cavity pair. Once the core is positioned in the firstmold cavity, the respective second mold cavity is mated to the first toclose the mold. A cover material is then injected into the closed mold.The positioning pins are retracted while the cover material is flowableto allow the material to fill in any holes caused by the pins. When thematerial is at least partially cured, the covered core is removed fromthe mold.

As with injection molding, compression molds typically include multiplepairs of mold cavities, each pair comprising first and second moldcavities that mate to form a spherical recess. In one exemplarycompression molding process, a cover material is preformed intohalf-shells, which are placed into a respective pair of compression moldcavities. The core is placed between the cover material half-shells andthe mold is closed. The core and cover combination is then exposed toheat and pressure, which cause the cover half-shells to combine and forma fall cover.

As with the above-referenced processes, a casting process also utilizespairs of mold cavities. In a casting process, a cover material isintroduced into a first mold cavity of each pair. Then, a core is heldin position (e.g. by an overhanging vacuum or suction apparatus) tocontact the cover material in what will be the spherical center of themold cavity pair. Once the cover material is at least partially cured(e.g., a point where the core will not substantially move), the core isreleased, the cover material is introduced into a second mold cavity ofeach pair, and the mold is closed. The closed mold is then subjected toheat and pressure to cure the cover material thereby forming a cover onthe core. With injection molding, compression molding, and casting, themolding cavities typically include a negative dimple pattern to impart adimple pattern on the cover during the molding process.

Materials previously used as golf ball covers include balata (natural orsynthetic), gutta-percha, ionomeric resins (e.g., DuPont's SURLYN(®),and polyurethanes. Balata is the benchmark cover material with respectto sound (i.e. the sound made when the ball is hit by a golf club) andfeel (i.e. the sensation imparted to the golfer when hitting the ball).Natural balata is derived from the Bully Gum tree, while syntheticbalata is derived from a petroleum compound. Balata is expensivecompared to other cover materials, and golf balls covered with balatatend to have poor durability (i.e. poor cut and shear resistance). Guttapercha is derived from the Malaysian sapodilla tree. A golf ball coveredwith gutta percha is considered to have a harsh sound and feel ascompared to balata covered golf balls.

Ionomeric resins, as compared to balata, are typically less expensiveand tend to have good durability. However, golf balls having ionomericresin covers typically have inferior sound and feel, especially ascompared to balata covers.

A golf ball with a polyurethane cover generally has greater durabilitythan a golf ball with a balata cover. The polyurethane covered golf ballgenerally has a better sound and feel than a golf ball with an ionomericresin cover. Polyurethanes may be thermoset or thermoplastic. Severalpatents describe the use of polyurethanes in golf balls.

Gallagher, U.S. Pat. No. 3,034,791 discloses a polyurethane golf ballcover prepared from the reaction product of poly(tetramethylene ether)glycol and toluene-2,4-diisocyanates (TDI), either pure TDI or anisomeric mixture.

Isaac, U.S. Pat. No. 3,989,568 (“the '568 patent) discloses apolyurethane golf ball cover prepared from prepolymers and curing agentsthat have different rates of reaction so a partial cure can be made. The'568 patent explains that “the minimum number of reactants is three.”Specifically, in '568 patent, two or more polyurethane prepolymers arereacted with at least one curing agent, or at least one polyurethaneprepolymer is reacted with two or more curing agents as long as thecuring agents have different rates of reaction.

Similar to Isaac, PCT International Publication Number WO 99/43394 toDunlop Maxfli Sports Corporation, discloses using two curing agents tocontrol the reaction time for polyurethane formation. The two curingagents are a dimethylthio 2,4-toluenediamine and diethyl2,4-toluenediamine, which are blended to control the reaction rate of atoluene diisocyanate based polyurethane prepolymer or a4,4′-diphenylmethane diisocyanate based polyurethane prepolymer.

Dusbiber, U.S. Pat. No. 4,123,061 (“the '061 patent”) discloses apolyurethane golf ball cover prepared from the reaction product of apolyether, a diisocyanate and a curing agent. The '061 patent disclosesthat the polyether may be polyalkylene ether glycol orpolytetramethylene ether glycol. The '061 patent also discloses that thediisocyanate may be TDI, 4,4′-diphenylmethane diisocyanate (“MDI”), and3,3′-dimethyl-4,4′-biphenylene diisocyanate (“TODI”).

Hewitt, et al., U.S. Pat. No. 4,248,432 (“the '432 patent”) discloses athermoplastic polyesterurethane golf ball cover formed from a reactionproduct of a polyester glycol (molecular weight of 800-1500) (aliphaticdiol and an aliphatic dicarboxylic acid) with a para-phenylenediisocyanate (“PPDI”) or cyclohexane diisocyanate in the substantialabsence of curing or crosslinking agents.

Holloway, U.S. Pat. No. 4,349,657 (“the '657 patent”) discloses a methodfor preparing polyester urethanes with PPDI by reacting a polyester(e.g. prepared from aliphatic glycols having 2-8 carbons reacted withaliphatic dicarboxylic acids having 4-10 carbons) with a molar excess ofPPDI to obtain an isocyanate-terminated polyester urethane (in liquidform and stable at reaction temperatures), and then reacting thepolyester urethane with additional polyester.

Wu, U.S. Pat. No. 5,334,673 (“the '673 patent”) discloses a polyurethaneprepolymer cured with a slow-reacting curing agent selected fromslow-reacting polyamine curing agents and difunctional glycols (i.e.,3,5-dimethylthio-2,4-toluenediamine,3,5-dimethylthio-2,6-toluenediamine, N,N′-dialkyldiamino diphenylmethane, trimethyleneglycol-di-p-aminobenzoate,polytetramethyleneoxide-di-p-aminobenzoate, 1,4-butanediol,2,3-butanediol, 2,3-dimethyl-2,3-butanediol, ethylene glycol, andmixtures of the same). The polyurethane prepolymer in the '673 patent isdisclosed as made from a polyol (e.g., polyether, polyester, orpolylactone) and a diisocyanate such as MDI or TODI. The polyetherpolyols disclosed in the '673 patent are polytetramethylene etherglycol, poly(oxypropylene) glycol, and polybutadiene glycol. Thepolyester polyols disclosed in the '673 patent are polyethylene adipateglycol, polyethylene propylene adipate glycol, and polybutylene adipateglycol. The polylactone polyols disclosed in the '673 patent arediethylene glycol initiated caprolactone, 1,4-butanediol initiatedcaprolactone, trimethylol propane initiated caprolactone, and neopentylglycol initiated caprolactone.

Wu, et al., U.S. Pat. No. 5,692,974 discloses golf balls having coversand cores that incorporate urethane ionomers (i.e. using an alkylatingagent to introduce ionic interactions in the polyurethane and therebyproduce cationic type ionomers).

Hebert, et al., U.S. Pat. No. 5,885,172 (“the '172 patent”) discloses amultilayer golf ball giving a “progressive performance” (i.e. differentperformance characteristics when struck with different clubs atdifferent head speeds and loft angles) and having an outer cover layerformed of a thermoset material with a thickness of less than 0.05 inchesand an inner cover layer formed of a high flexural modulus material. The'172 patent provides that the outer cover is made from polyurethaneionomers as described in Wu, et al., U.S. Pat. No. 5,692,974, orthermoset polyurethanes such as TDI or methylenebis-(4-cyclohexylisocyanate) (“HMDI”), or a polyol cured with a polyamine (e.g.methylenedianiline (MDA)), or with a trifunctional glycol (e.g.,N,N,N′,N′-tetrakis(2-hydroxpropyl)ethylenediamine).

Wu, U.S. Pat. No. 5,484,870 (“the '870 patent”) discloses golf ballshaving covers composed of a polyurea composition. The polyureacomposition disclosed in the '870 patent is a reaction product of anorganic isocyanate having at least two functional groups and an organicamine having at least two functional groups. One of the organicisocyanates disclosed by the '870 patent is PPDI.

What is missing from the prior art is a two-piece golf ball with anoversize core and a durable cover.

BRIEF SUMMARY OF THE INVENTION

The present invention provides an oversize core with a durable coverthrough the use of reaction injection molding a polyurethane cover overan oversize core.

One aspect of the present invention is a two-piece golf ball comprisinga core and a cover. The core has a diameter ranging from 1.610 inches to1.670 inches. The cover has a thickness ranging from 0.015 inch to 0.045inch. The cover is composed of a reaction injection molded polyurethanematerial. The golf ball has a diameter ranging from 1.680 inches to1.685 inches.

Another aspect of the present invention is a two-piece golf ball havinga diameter ranging from 1.680 inches to 1.72 inches. The golf ball has acore with a volume ranging from 90 to 95% of the volume of the golf balland a cover having a volume ranging 5% to 10% of the golf ball. Thecover is composed of a reaction injection molded polyurethane material.

Another aspect of the present invention is a two-piece golf ball havinga core with a volume ranging from 38 cubic centimeters to 40 cubiccentimeters, and a cover with a volume ranging from 2 cubic centimetersto 3 cubic centimeters. The cover is composed of a reaction injectionmolded polyurethane material. The golf ball has a diameter ranging from1.680 inches to 1.72 inches.

Having briefly described the present invention, the above and furtherobjects, features and advantages thereof will be recognized by thoseskilled in the pertinent art from the following detailed description ofthe invention when taken in conjunction with the accompanying drawings.

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

FIG. 1 illustrates a perspective view of a golf ball of the presentinvention including a cut-away portion core and a cover.

FIG. 2 is a cross-sectional view of a golf ball of the presentinvention.

FIG. 2A is a cross-sectional view of an alternative embodiment of a golfball of the present invention.

FIG. 3 is a process flow diagram which schematically depicts a reactioninjection molding process according to the invention.

FIG. 4 schematically shows a mold for reaction injection molding a golfball cover according to the invention.

DETAILED DESCRIPTION OF THE INVENTION

As illustrated in FIGS. 1, 2 and 2A, a golf ball is generally indicatedas 10. The two-piece golf ball 10 preferably includes a core 12 and acover 16. The cover 16 is composed of a reaction injection moldedpolyurethane material. In a preferred embodiment, the cover 16 is formedover the core 12. The core 12 is of a larger size than convention coresthereby allowing for greater distance. The core 12 is capable ofobtaining a larger size due to the thinness of the cover 16, which isformed by reaction injection molding.

As shown in FIG. 2A, the cover preferably has a plurality of deepapertures 21 extending through the cover 16. The cover 16 alsopreferably has a plurality of dimples 20. Those skilled in the art willrecognize that the core may be solid, hollow, multi-piece orliquid-filled without departing from the scope and spirit of the presentinvention.

The cover 16 is formed by reaction injection molding (“RIM”) asdescribed below. The core 12 is formed using conventional methods wellknown in the pertinent art.

In a preferred embodiment, the core 12 is solid. The solid core 12 forthe golf ball 10 is preferably about 1.2-1.6 inches in diameter,although it may be possible to use cores in the range of about 1.0-2.0inches. Conventional solid cores are typically compression or injectionmolded from a slug or ribbon of uncured or lightly cured elastomercomposition comprising a high cis content polybutadiene and metal saltof an α, β, ethylenically unsaturated carboxylic acid such as zinc monoor diacrylate or methacrylate. Preferably, the core comprises at leasttow polybutadiene materials, each having a different Mooney viscosity, azinc oxide material, a zinc stearate material, a zinc diacrylatematerial and a peroxide material. The core 12 of the present inventionis preferably a single solid core such as disclosed in U.S. Pat. No.6,612,940, assigned to Callaway Golf Company and which pertinent partsare hereby incorporated by reference, or such as disclosed in U.S. Pat.No. 6,465,546, also assigned to Callaway Golf Company and whichpertinent parts are hereby incorporated by reference. However,alternative embodiments have a non-solid or multiple cores such asdisclosed in U.S. Pat. No. 6,663,509, which pertinent parts are herebyincorporated by reference.

The core 12 preferably has a diameter in the range of 1.610 inches to1.670 inches. The cover 16 is preferably about 0.015 inch to about 0.045inch in thickness. Together, the core 12 and the cover 16 combine toform a golf ball 10 preferably having a diameter of 1.680 inches ormore, the minimum diameter permitted by the rules of the United StatesGolf Association and weighing no more than 1.62 ounces.

The cover 16 comprises at least one material selected from the groupconsisting of polyurethane, polyurea, polyurethane ionomer, epoxy, andunsaturated polyesters, and preferably comprises polyurethane. Thematerial of the cover 16 preferably has a flex modulus in the range of5,000 to 310,000 pounds per square inch (“psi”), a Shore D hardness inthe range of 20 to 90, good durability, and good scuff resistance andcut resistance. As used herein, “polyurethane and/or polyurea” isexpressed as “polyurethane/polyurea”.

Referring to FIG. 3, a preferred embodiment of a process flow diagramfor forming a RIM cover 16. An isocyanate component from bulk storage isfed through line 80 to an isocyanate tank 100. The isocyanate componentis preferably comprises a 4,4′-diphenylmethane diisocyanate (“MDI”).Alternatively, the isocyanate component comprises an isocyanate selectedfrom the group consisting of 3,3′-dimethyl-4,4′-biphenylene diisocyanate(“TODI”), para-phenylene diisocyanate (“PPDI”), andtoluene-2,4-diisocyanates (TDI). The polyol component preferablycomprises a polyamine, polyester and similar materials. Polyurethanematerials suitable for the present invention may be formed by thereaction of a polyisocyanate, a polyol, and optionally one or more chainextenders. The polyol component includes any suitable polyether- orpolyester polyol. Additionally, in an alternative embodiment, the polyolcomponent is polybutadiene diol. The chain extenders include, but arenot limited to, diols, triols and amine extenders. Any suitablepolyisocyanate may be used to form a polyurethane according to thepresent invention. The polyisocyanate is preferably selected from thegroup of diisocyanates including, but not limited to,4,4′-diphenylmethane diisocyanate (“MDI”); 2,4-toluene diisocyanate(“TDI”); m-xylylene diisocyanate (“XDI”); methylene bis-(4-cyclohexylisocyanate) (“HMDI”); hexamethylene diisocyanate (“HDI”);naphthalene-1,5,-diisocyanate (“NDI”); 3,3′-dimethyl-4,4′-biphenyldiisocyanate (“TODI”); 1,4-diisocyanate benzene (“PPDI”);phenylene-1,4-diisocyanate; and 2,2,4- or 2,4,4-trimethyl hexamethylenediisocyanate (“TMDI”).

Other less preferred diisocyanates include, but are not limited to,isophorone diisocyanate (“IPDI”); 1,4-cyclohexyl diisocyanate (“CHDI”);diphenylether-4,4′-diisocyanate; p,p′-diphenyl diisocyanate; lysinediisocyanate (“LDI”); 1,3-bis (isocyanato methyl) cyclohexane; andpolymethylene polyphenyl isocyanate (“PMDI”).

One additional polyurethane component which can be used in the presentinvention incorporates TMXDI (“META”) aliphatic isocyanate (CytecIndustries, West Paterson, N.J.). Polyurethanes based onmeta-tetramethylxylylene diisocyanate (TMXDI) can provide improved glossretention UV light stability, thermal stability, and hydrolyticstability. Additionally, TMXDI (“META”) aliphatic isocyanate hasdemonstrated favorable toxicological properties. Furthermore, because ithas a low viscosity, it is usable with a wider range of diols (topolyurethane) and diamines (to polyureas). If TMXDI is used, ittypically, but not necessarily, is added as a direct replacement forsome or all of the other aliphatic isocyanates in accordance with thesuggestions of the supplier. Because of slow reactivity of TMXDI, it maybe useful or necessary to use catalysts to have practical demoldingtimes. Hardness, tensile strength and elongation can be adjusted byadding further materials in accordance with the supplier's instructions.

The polyurethane which is selected for use as a golf ball coverpreferably has a Shore D hardness (plaque) of from about 10 to about 55(Shore C of about 15 to about 75), more preferably from about 25 toabout 55 (Shore C of about 40 to about 75), and most preferably fromabout 30 to about 55 (Shore C of about 45 to about 75) for a soft coverlayer and from about 20 to about 90, preferably about 30 to about 80,and more preferably about 40 to about 70 for a hard cover layer.

The polyurethane which is to be used for a cover layer preferably has aflex modulus from about 1 to about 310 Kpsi, more preferably from about3 to about 100 Kpsi, and most preferably from about 3 to about 40 Kpsifor a soft cover layer and 40 to 90 Kpsi for a hard cover layer.Accordingly, covers comprising these materials exhibit similarproperties. The polyurethane preferably has good light fastness.

The isocyanate component is heated to the desired temperature, e.g. 90to about 150 degrees Fahrenheit (“° F.”), by circulating it through heatexchanger 82 via lines 84 and 86. Polyol component is conveyed from bulkstorage to a polyol tank 108 via line 88. The polyol blend is heated tothe desired temperature, e.g. 90 to about 150° F. by circulating itthrough heat exchanger 90 via lines 92 and 94. Dry nitrogen gas is fedfrom nitrogen tank 96 to isocyanate tank 100 via line 97 and to polyoltank 108 via line 98. The isocyanate component is fed from isocyanatetank 100 via line 102 through a metering cylinder or metering pump 104into recirculation mix head inlet line 106. The polyol component is fedfrom polyol tank 108 via line 110 through a metering cylinder ormetering pump 112 into a recirculation mix head inlet line 114. Therecirculation mix head 116 receives the isocyanate component and thepolyol component, mixes them, and provides for them to be fed throughnozzle 118 into injection mold 120. The injection mold 120 has a topmold 122 and a bottom mold 124. Mold heating or cooling can be performedthrough lines 126 in the top mold 122 and lines 140 in the bottom mold124. The materials are kept under controlled temperature conditions toinsure that the desired reaction profile is maintained.

The polyol component may also contain additives, such as stabilizers,flow modifiers, catalysts, combustion modifiers, blowing agents,fillers, pigments, optical brighteners, and release agents to modifyphysical characteristics of the cover.

Inside the mix head 116, injector nozzles impinge the isocyanate andpolyol blend at ultra-high velocity to provide excellent mixing.Additional mixing preferably is conducted using an aftermixer 130, whichtypically is constructed inside the mold between the mix head and themold cavity.

As is shown in FIG. 4, the mold includes a golf ball cavity chamber 132in which a spherical golf ball cavity 134 with an aerodynamic sphericalsurface 136 is defined. The aftermixer 130 can be a peanut aftermixer,as is shown in FIG. 3, or in some cases another suitable typeaftermixer, such as a heart, harp or dipper. However, the aftermixerdoes not have to be incorporated into the mold design. An overflowchannel 138 receives overflow material from the golf ball cavity 134through a shallow vent 142. Heating/cooling passages 126 and 140, whichpreferably are in a parallel flow arrangement, carry heat transferfluids such as water, oil, etc. through the top mold 122 and the bottommold 124.

The mold cavity preferably contains retractable pins and is generallyconstructed in the same manner as a mold cavity used to injection mold athermoplastic, e.g., ionomeric golf ball cover. However, two differenceswhen RIM is used are that tighter pin tolerances generally are required,and a lower injection pressure is used. Also, the molds can be producedfrom lower strength material such as aluminum.

Non-limiting examples of suitable RIM systems for use in the presentinvention are Bayflex® elastomeric polyurethane RIM systems, Baydur® GSsolid polyurethane RIM systems, Prism® solid polyurethane RIM systems,all from Bayer Corp. (Pittsburgh, Pa.), SPECTRIM reaction moldablepolyurethane and polyurea systems from Dow Chemical USA (Midland,Mich.), including SPECTRIM MM 373-A (isocyanate) and 373-B (polyol), andElastolit SR systems from BASF (Parsippany, N.J.). Preferred RIM systemsinclude Bayflex® MP-10000 and Bayflex® 110-50, filled and unfilled.Further preferred examples are polyols, polyamines and isocyanatesformed by processes for recycling polyurethanes and polyureas.Peroxides, such as MEK-peroxide and dicumyl peroxide can be used.Furthermore, catalysts or activators such as cobalt octoate 6% can beused in the RIM process.

RIM processes and materials that are useful in forming the golfball ofthe present invention are disclosed in the following U.S. Patents, allof which are hereby incorporated by reference in their entireties: U.S.Pat. No. 6,290,614 for a Golf Ball Which IncludesFast-Chemical-Reaction-Produced Component And Method Of Making Same;U.S. Pat. No. 6,533,566 for an Apparatus For Making A Golf Ball; U.S.Pat. No. 6,716,954 for a Golf Ball Formed From A PolyisocyanateCopolymer And Method Of Making Same; U.S. Pat. No. 6,755,634 for anApparatus For Forming A Golf Ball With Deep Dimples; U.S. Pat. No.6,776,731 for an Apparatus And Process For Forming A Golf Ball With DeepDimples; and, U.S. Pat. No. 6,790,149 for a Golf Ball.

The golf ball 10 formed according to the present invention can be coatedusing a conventional two-component spray coating or can be coated duringthe RIM process, i.e., using an in-mold coating process. After molding,the golf ball 10 produced may undergo various further processing stepssuch as buffing, painting and marking as disclosed in U.S. Pat. No.4,911,451, which pertinent parts are hereby incorporated by reference.

During the RIM process, the chemical reaction, i.e., the mixture ofisocyanate component from the isocyanate tank and polyol component fromthe polyol tank, occurs during the molding process. Specifically, themixing of the reactants occurs in the recirculation mix head and theafter mixer, both of which are connected directly to the injection mold.The reactants are simultaneously mixed and injected into the mold,forming the desired component.

Typically, prior art techniques utilize mixing of reactants to occurbefore the molding process. Mixing under either compression or injectionmolding occurs in a mixer that is not connected to the moldingapparatus. Thus, the reactants must first be mixed in a mixer separatefrom the molding apparatus, then added into the apparatus. Such aprocess causes the mixed reactants to first solidify, then later melt inorder to properly mold.

The RIM process also allows for lower temperatures and pressures duringmolding than does injection or compression molding. Under the RIMprocess, the molding temperature is maintained at about 100-120° F. inorder to ensure proper injection viscosity. In comparison, compressionmolding is typically completed at a higher molding temperature of about320° F. an injection molding is completed at even a higher temperaturerange of 392-482° F. . Molding at a lower temperature is beneficialwhen, for example, the cover is molded over a very soft core so that thevery soft core does not melt or decompose during the molding process.

The RIM process also creates more favorable durability properties in agolf ball than does conventional injection or compression molding. Thepreferred process of the present invention provides improved durabilityfor a golf ball cover by providing a uniform or “seamless” cover inwhich the properties of the cover material in the region along theparting line are generally the same as the properties of the covermaterial at other locations on the cover, including at the poles. Theimprovement in durability is due to the fact that the reaction mixtureis distributed uniformly into a closed mold. This uniform distributionof the injected materials eliminates knit-lines and other moldingdeficiencies which can be caused by temperature difference and/orreaction difference in the injected materials. The RIM process of thepresent invention results in generally uniform molecular structure,density and stress distribution as compared to conventional injectionmolding processes, where failure along the parting line or seam of themold can occur because the interfacial region is intrinsically differentfrom the remainder of the cover layer and, thus, can be weaker or morestressed.

The RIM process also is relatively faster than the conventionalinjection and compression molding techniques. In the RIM process, thechemical reaction takes place in under 5 minutes, typically in less thantwo minutes, preferably in under one minute and, in many cases, in about30 seconds or less. The demolding time of the present application is 10minutes or less. The molding process alone for the conventional methodstypically take about 15 minutes. Thus, the overall speed of the RIMprocess makes it advantageous over the injection and compression moldingmethods.

The core 12 typically have a coefficient of restitution of about 0.750or more, more preferably 0.770 or more and a PGA compression of about 90or less, and more preferably 70 or less, and most preferably from 40 to60. The core used in the golf ball of the invention preferably is solid.The term “solid cores” as used herein refers not only to one piece coresbut also to those cores having a separate solid layer beneath the coversand over the central core. The cores have a weight of 35-41 grams. Whenthe golf ball of the invention has a solid core, this core can becompression molded from a slug of uncured or lightly cured elastomercomposition comprising a high cis content polybutadiene and a metal saltof an α, β, ethylenically unsaturated carboxylic acid such as zinc mono-or diacrylate or methacrylate. To achieve higher coefficients ofrestitution and/or to increase hardness in the core, the manufacturermay include a small amount of a metal oxide such as zinc oxide. Inaddition, larger amounts of metal oxide than are needed to achieve thedesired coefficient may be included in order to increase the core weightso that the finished ball more closely approaches the U.S.G.A. upperweight limit of 1.620 ounces. Non-limiting examples of other materialswhich may be used in the core composition including compatible rubbersor ionomers, and low molecular weight fatty acids such as stearic acid.Free radical initiator catalysts such as peroxides are admixed with thecore composition so that on the application of heat and pressure, acuring or cross-linking reaction takes place.

The thickness of the cover 16 preferably ranges from 0.015 inch to 0.045inch, more preferably ranges from 0.020 inch to 0.030 inch.

The Shore D hardness of the golf ball 10, as measured on the golf ball,is preferably between 40 Shore D points to 75 Shore D points, and mostpreferably between 50; Shore D points and 65 Shore D points. Thehardness of the golf ball 10 is measured using an Instron Shore DHardness measurement device wherein the golf ball 10 is placed within aholder and the pin is lowered to the surface to measure the hardness.The average of five measurements is used in calculating the ballhardness. The ball hardness is preferably measured on a land area of thecover 14. The preferred overall diameter of the golf ball 10 isapproximately 1.68 inches, and the preferred mass is approximately 45.5grams. However, those skilled in the pertinent art will recognize thatthe diameter of the golf ball 10 may be larger ( e.g. 1.70 inches or1.72 inches) without departing from the scope and spirit of the presentinvention. Further, the mass may also vary without departing from thescope and spirit of the present invention. The golf ball preferably hasa PGA compression ranging from 50 to 70, and a coefficient ofrestitution ranging from 0.78 to 0.81.

The surface geometry of the golf ball 10 is preferably a conventionaldimple pattern such as disclosed in U.S. Pat. No. 6,213,898 for a GolfBall With An Aerodynamic Surface On A Polyurethane Cover, whichpertinent parts are hereby incorporated by reference. Alternatively, thesurface geometry of the golf ball 10 may have a non-dimple pattern suchas disclosed in U.S. Pat. No. 6,290,615 for A Golf Ball Having Tubularlattice Pattern, which pertinent parts are hereby incorporated byreference.

From the foregoing it is believed that those skilled in the pertinentart will recognize the meritorious advancement of this invention andwill readily understand that while the present invention has beendescribed in association with a preferred embodiment thereof, and otherembodiments illustrated in the accompanying drawings, numerous changes,modifications and substitutions of equivalents may be made thereinwithout departing from the spirit and scope of this invention which isintended to be unlimited by the foregoing except as may appear in thefollowing appended claims. Therefore, the embodiments of the inventionin which an exclusive property or privilege is claimed are defined inthe following appended claims.

1. A golf ball comprising: a core having a diameter ranging from 1.610 inches to 1.670 inches, the core having multiple layers, the core having a volume ranging from 38 cubic centimeters to 40 cubic centimeters; a cover having a thickness ranging from 0.015 inch to 0.045 inch, the cover having a volume ranging from 2 cubic centimeters to 3 cubic centimeters, the cover having a plurality of deep apertures extending through the cover; wherein the golf ball has a diameter ranging from 1.680 inches to 1.685 inches.
 2. A golf ball comprising: a core having a volume ranging from 90 to 95% of the volume of the golf ball, the core having a diameter ranging from 1.610 inches to 1.670 inches, the core having multiple layers; a cover having a volume ranging 5% to 10% of the golf ball, the cover having a thickness ranging from 0.015 inch to 0.045 inch, the cover having a plurality of deep apertures extending through the cover; wherein the golf ball has a diameter ranging from 1.680 inches to 1.72 inches. 